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vanadate
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Definitions of vanadate in various dictionaries:
noun - a salt or ester of vanadic acid
noun - a chemical salt
VANADATE - In chemistry, a vanadate is a compound containing an oxoanion of vanadium generally in its highest oxidation state of +5. The simplest vanadate ion i...
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In chemistry, a vanadate is a compound containing an oxoanion of vanadium generally in its highest oxidation state of +5. The simplest vanadate ion is the tetrahedral, orthovanadate, VO34 anion, which is present in e.g. sodium orthovanadate and in solutions of V2O5 in strong base (pH > 13 ). Conventionally this ion is represented with a single double bond, however this is a resonance form as the ion is a regular tetrahedron with four equivalent oxygen atoms. * Additionally a range of polyoxovanadate ions exist which include discrete ions and "infinite" polymeric ions. There are also vanadates, such as rhodium vanadate, RhVO4, which has a statistical rutile structure where the Rh3+ and V5+ ions randomly occupy the Ti4+ positions in the rutile lattice, that do not contain a lattice of cations and balancing vanadate anions but are mixed oxides. * In chemical nomenclature when vanadate forms part of the name, it indicates that the compound contains an anion with a central vanadium atom, e.g. a |