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thiocyanates
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Definitions of thiocyanates in various dictionaries:
noun - a salt of thiocyanic acid
THIOCYANATES - Thiocyanate (also known as rhodanide) is the anion [SCN]. It is the conjugate base of thiocyanic acid. Common derivatives include the colourless sa...
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Thiocyanate (also known as rhodanide) is the anion [SCN]. It is the conjugate base of thiocyanic acid. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. Organic compounds containing the functional group SCN are also called thiocyanates. Mercury(II) thiocyanate was formerly used in pyrotechnics. * Thiocyanate is analogous to the cyanate ion, [OCN], wherein oxygen is replaced by sulfur. [SCN] is one of the pseudohalides, due to the similarity of its reactions to that of halide ions. Thiocyanate used to be known as rhodanide (from a Greek word for rose) because of the red colour of its complexes with iron. Thiocyanate is produced by the reaction of elemental sulfur or thiosulfate with cyanide:* 8 CN + S8 8 SCN * CN + S2O23 SCN + SO23The second reaction is catalyzed by thiosulfate sulfurtransferase, a hepatic mitochondrial enzyme, and by other sulfur transferases, which together are responsible for around 80% of cyanide metabolism in |