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imidic

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Definitions of imidic in various dictionaries:

adj - a chemical compound [n -S] : IMIDIC

IMIDIC - In chemistry, an imidic acid is any molecule that contains the -C(=NH)-OH functional group. It is the tautomer of an amide and the isomer of an oxime...

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Of or pertaining to imides or to imidic acids

Imidic might refer to
In chemistry, an Imidic acid is any molecule that contains the -C(=NH)-OH functional group. It is the tautomer of an amide and the isomer of an oxime. * The term "imino acid" is an obsolete term for this group that should not be used in this context because an imino acid has a different technical meaning.Imidic acids can be formed by metal-catalyzed dehydrogenation of geminal amino alcohols. For example, methanolamine, the parent compound of the amino alcohols, can be dehydrogenated to methanimidic acid, the parent compound of the imidic acids.* H2NCH2OH → HNCHOH + H2 (tautomer of formamide)Geminal amino alcohols with side chains similarly form imidic acids with the same side chains: * * H2NCHROH → HNCROH + H2Another way to form imidic acids is the reaction of carboxylic acids with azanone. For example, the reaction for carbamic acid: * * H2NCOOH + HNO → H2NCNHOH + O2 (tautomer of urea)And the general reaction for substituted imidic acids: * * RCOOH + R'NO → RCNR'OH + O2Another mechanism is the reaction of carboxylic acids with diazene or other azo compounds, forming azanone. * * RCOOH + HNNH → RCNHOH + HNOImidic acids tautomerize to amides by a hydrogen shift from the oxygen to the nitrogen atom. Amides are more stable in an environment with oxygen or water, whereas imidic acids dominate the equilibrium in solution with ammonia or methane. * * HNCHOH ⇌ HCONH2RNCR'OH ⇌ R'CONHR

Imidic might refer to

In chemistry, an Imidic acid is any molecule that contains the -C(=NH)-OH functional group. It is the tautomer of an amide and the isomer of an oxime.
* The term "imino acid" is an obsolete term for this group that should not be used in this context because an imino acid has a different technical meaning.Imidic acids can be formed by metal-catalyzed dehydrogenation of geminal amino alcohols. For example, methanolamine, the parent compound of the amino alcohols, can be dehydrogenated to methanimidic acid, the parent compound of the imidic acids.* H2NCH2OH → HNCHOH + H2 (tautomer of formamide)Geminal amino alcohols with side chains similarly form imidic acids with the same side chains:
*
* H2NCHROH → HNCROH + H2Another way to form imidic acids is the reaction of carboxylic acids with azanone. For example, the reaction for carbamic acid:
*
* H2NCOOH + HNO → H2NCNHOH + O2 (tautomer of urea)And the general reaction for substituted imidic acids:
*
* RCOOH + R'NO → RCNR'OH + O2Another mechanism is the reaction of carboxylic acids with diazene or other azo compounds, forming azanone.
*
* RCOOH + HNNH → RCNHOH + HNOImidic acids tautomerize to amides by a hydrogen shift from the oxygen to the nitrogen atom. Amides are more stable in an environment with oxygen or water, whereas imidic acids dominate the equilibrium in solution with ammonia or methane.
*
* HNCHOH ⇌ HCONH2RNCR'OH ⇌ R'CONHR

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