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cyanohydrins
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Definitions of cyanohydrins in various dictionaries:
noun - any organic compound in which the cyano radical -CN and the hydroxyl radical -OH are attached to the same carbon atom
CYANOHYDRINS - A cyanohydrin is a functional group found in organic compounds in which a cyano and a hydroxy group are attached to the same carbon atom. The genera...
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Plural form of cyanohydrin. |
An organic compound containing a carbon atom linked to both a cyanide group and a hydroxyl group. |
Cyanohydrins might refer to |
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A Cyanohydrin is a functional group found in organic compounds in which a cyano and a hydroxy group are attached to the same carbon atom. The general formula is R2C(OH)CN, where R is H, alkyl, or aryl. Cyanohydrins are industrially important precursors to carboxylic acids and some amino acids. Cyanohydrins can be formed by the cyanohydrin reaction, which involves treating a ketone or an aldehyde with hydrogen cyanide (HCN) in the presence of excess amounts of sodium cyanide (NaCN) as a catalyst: * RRC=O + HCN RRC(OH)CNIn this reaction, the nucleophilic CN ion attacks the electrophilic carbonyl carbon in the ketone, followed by protonation by HCN, thereby regenerating the cyanide anion. Cyanohydrins are also prepared by displacement of sulfite by cyanide salts: * Cyanohydrins are intermediates in the Strecker amino acid synthesis. |